Just keeping this up to date...
The garage sent the head off yesterday to an engine specialist who I've contacted direct. It not only needs a skim and new gaskets but all the valves replacing. The bill for this is £580 not including refitting.
I'm rather perturbed that I didn't go to them in the first place and always at the back of my mind I know the car was out of time but drivable as I dropped it off. I wonder at what point the valves got bent!