Got to the bottom of this one and fixed it
Last night, fitted new exhaust centre section so now I have complete new exhaust instead of 2inch downpipe, 2.5inch centre into 2inch backbox. Rattle was still there, removed heat shield, rattle still there and disconnected EGR, rattle still there.
Got missus to rev car to 4k at idle, rattle like crazy. Got stethoscope out and tested again, the rattle was coming from the exhaust cam area. Stripped off cam cover and found that 1 and 5 cam end caps were significantly loose with 2 and 4 being a little loose. Remembered that when we swapped heads, I swapped the exhaust cam out of the old head and put it in the new one. Thought I had done these to 10nm as per Vx spec but obviously the gremlins had tried to sabotage my plans for a smooth 2.2
Circle tightened to 10nm, reset everything and took for test drive. The Vectra is super smooth again - result, fixed!